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NACURE® & K-CURE®
ACID AND BLOCKED ACID CATALYSTS

Why Use Catalysts?

In order to meet the environmental demands of lower solvent emissions, much of today's high solids and waterborne coatings are based upon low molecular weight resins and amino-formaldehyde crosslinkers. Conversion of these systems into tough, chemically resistant, high performance films at reasonable cure temperatures requires the use of catalysts.

Common backbone resins in these formulations include acrylics, alkyds, epoxies and polyesters. Typical amino crosslinking agents include melamines, ureas, glycolurils and benzoguanamines. Reaction of the backbone resin with an amino crosslinker can be greatly enhanced by the addition of the appropriate catalyst. As a result, the reaction between the functional groups of the resin and the crosslinker can be effectively controlled, thus offering:

Cure response capabilities from room temperature for acid catalysts and from 65ºC for blocked catalysts
Lower cure temperatures for thermoset high solids and waterborne coatings

Additionally, the proper choice of catalyst can impart specific desirable properties to the coating including:

Improved hardness, gloss, humidity and corrosion resistance
Improved mechanical properties

King Industries was a pioneer in the development of catalysts and today offers the most complete line of acid and blocked acid (latent) catalysts available.

While acid catalysts provide the fastest cure and lower curing temperatures, blocked catalysts are typically chosen for systems requiring greater package stability. In addition, troublesome catalyst-pigment interaction is reduced or eliminated.

Suggested Starting Levels Acid Catalysts

(Table 1) lists acid catalysts and (Table 3) blocked acid catalysts to fulfill your specific needs.

(Table 2) represents the various cure profiles of the acid catalyst based upon a 30 minute cure schedule for a typical Resin/HMMM (75/25 ratio) coating.


(Chart 1 - 26KB) shows typical use level for the blocked catalysts based on their acid type for the same typical Resin/HMMMM coating with a 30 minute cure schedule.

 


Table 1
Nacure® and K-Cure® Acid Catalysts
Product Acid Type
Volatile
% Active Acid # Lbs/Gal Gardner
Color
Min.*
Cure
Attributes/Uses
Nacure
155
DNNDSA
Isobutanol
55 112-116 8.16 12 max. RT General purpose catalyst. Excellent water, detergent and salt spray resistance.
Nacure
1051
DNNSA
2-Butoxyethanol
50 60-64 8.16 n/a 125°C Best water and corrosion resistance. Recommended for high temperature applications on metal.
Nacure
5076
DDBSA
Isopropanol
70 130-140 8.17 4 RT Complies with FDA 21 CFR, Sec. 175.300 (b) (3) xiii (a&b).
Nacure
4054
AAP
Isobutanol
50 155-165 7.49 1 110°C Weak acid for high NH/polymeric melamines and phenolic crosslinkers. 4054J for RT cure.
K-Cure
1040
p-TSA
Isopropanol
40 130-140 8.25 1 RT Highest gloss. Fastest cure. Excellent weathering and exterior durability.
K-Cure
1040W
p-TSA
Water
40 130-140 9.40 2 RT As above, non-flammable for WB applications.
K-Cure
129B
Mixed Acids
Methanol/n-Butanol
50 200-210 8.90 1 RT Fastest cure. Wood and paper coatings.
K-Cure
129W
Mixed Acids
Water
50 200-210 9.85 1 RT Non-flammable, WB ink and wood coatings.
RT=Room Temperature, *30 minute cure schedule - Resin/Urea (60/40 ratio)

 

 

Table 2
Acid Catalysts - Suggested Starting Levels
Product 70°C 90°C 110°C 125°C 150°C 175°C 200°C
N-155 4.7% 2.7% 1.6% 1.2% 0.6% 0.5% 0.3%
N-1051 NR NR NR 2.2% 1.4% 0.9% 0.6%
N-5076 4.5% 2.5% 1.5% 1.1% 0.7% 0.5% 0.3%
N-4054** NR NR 4.0% 2.0% 1.0% NR NR
K-1040/1040W 4.2% 2.3% 1.4% 1.0% 0.7% 0.4% 0.3%
K-129B/129W 2.6% 1.5% 0.9% 0.7% 0.4% 0.3% 0.2%
**30 min. cure schedule, catalyst (as supplied) on Total Resin Solids - High NH Polymeric melamine, NR=Not Recommended

 

 

Table 3
Nacure® Blocked Catalysts
Product Acid Type
Volatile
% Active pH Lbs/Gal Gardner
Color
Min.*
Cure
Attributes/Uses
Nacure
X49-110
DNNDSA
Isobutanol/
Isopropanol
25 6.5 - 7.5 7.55 10 max. 90°C Best overall properties. Excellent water and corrosion resistance, adhesion.
Nacure
3525
DNNDSA
Isobutanol/
Isopropanol
25 7.0 - 8.5 7.65 10 max. 120°C Better solubility than X49, slower curing. Good salt spray resistance and adhesion.
Nacure*
XP-383
DNNDSA
Xylene
25 n/a 8.20 10 max. 120°C Low conductivity for electrostatic spray. High gloss, reduced pigment interaction.
Nacure
3327
DNNDSA
Isobutanol/
Isopropanol
25 6.5 - 7.5 7.40 10 max. 107°C Better solubility than other amine blocked DSA catalysts.
Nacure
1323
DNNSA
Xylene
21 6.8 - 7.5 7.43 n/a 150°C High temperature applications. Excellent solubility in aromatic and aliphatic solvents.
Nacure*
1419
DNNSA
Xylene/
MIBK
30 n/a 7.74 n/a 150°C Electrostatic spray. High bake applications for water, detergent and salt spray resistance.
Nacure
1557
DNNSA
Butanol/
2-Butoxyethanol
25 6.5 - 7.5 7.56 n/a 150°C Resolves solvent popping in thick films.  Excellent humidity and detergent resistance.
Nacure
5225
DDBSA
Isopropanol
25 6.0 - 7.0 7.40 2 120°C Best solubility in high solids enamels. Good solubility in aliphatic solvents.
Nacure*
5414
DDBSA
Xylene
25 n/a 8.30 4 120°C Polymeric blocked. Excellent electrostatic spray (non-aqueous). Good intercoat adhesion.
Nacure
5528
DDBSA
Isopropanol
25 7.0 - 8.0 7.50 2 120°C Broad solubility. Excellent color stability.
Nacure
5925
DDBSA
Isopropanol
25 7.0 - 7.5 7.50 2 130°C Complies with FDA 21 CFR, Sec. 175.300 (b) (3) xiii (a&b).
Nacure
2107
p-TSA
Isopropanol
25 8.0 - 9.0 7.57 1 90°C Good metal mark resistance.
Nacure
2500
p-TSA
Isopropanol
26 6.0 - 7.0 8.15 1 65°C Low temperature cure. Excellent stability.
Nacure
2501
TSA
Methanol/
Isopropanol
25 6.0 - 7.2 8.01 1 80°C Slightly higher resistivity than 2500. Better ketone solubility.
Nacure
2530
p-TSA
Methanol/
Isopropanol
25 5.7 - 6.5 7.90 1 65°C Low temperature cure. Low tendency to yellow or wrinkle.
Nacure
2547
p-TSA
Water
25 8.0 - 9.0 9.18 1 107°C Readily soluble in waterborne systems. Solvent-free.
Nacure
2558
p-TSA
Ethylene
Glycol
25 3.5 - 4.5 9.64 1 80°C Excellent control of popping/blistering.
Nacure
XP-357
p-TSA
Methanol
20 2.0 - 4.0 8.00 1 65°C Rapid cure, very low tendency to yellow.
Nacure
XP-386
p-TSA
Water
47 6.1 - 6.4 9.29 1 80°C Fast cure for laminating adhesives and WB coatings.
Nacure
XP-2211
p-TSA
Water
54 7.2 - 8.5 9.80 1 80°C Rapid cure for thermoset waterbornes. Overprint varnish.
Nacure
4167
Acid Phosphate
Isopropanol/
Isobutanol
25 6.8 - 7.3 7.16 2 80°C Blocked phosphate for high NH/polymeric melamines. Good stability.
Nacure
XP-297
Acid Phosphate
Water/
Isopropanol
25 6.5 - 7.5 8.20 2 90°C Aqueous systems using high NH/polymeric melamines.
Nacure
XP-4575
Acid Phosphate
Methanol/
Butanol
25 7.0 - 8.0 8.3 2 110°C High gloss. Superb storage stability with polymeric amino resins.
* Covalently blocked products, n/a=Not Applicable

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