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| NACURE® & K-CURE® ACID AND BLOCKED ACID CATALYSTS Why Use Catalysts? In order to meet the environmental demands of lower solvent emissions, much of today's high solids and waterborne coatings are based upon low molecular weight resins and amino-formaldehyde crosslinkers. Conversion of these systems into tough, chemically resistant, high performance films at reasonable cure temperatures requires the use of catalysts. Common backbone resins in these formulations include acrylics, alkyds, epoxies and polyesters. Typical amino crosslinking agents include melamines, ureas, glycolurils and benzoguanamines. Reaction of the backbone resin with an amino crosslinker can be greatly enhanced by the addition of the appropriate catalyst. As a result, the reaction between the functional groups of the resin and the crosslinker can be effectively controlled, thus offering:
Additionally, the proper choice of catalyst can impart specific desirable properties to the coating including:
King Industries was a pioneer in the development of catalysts and today offers the most complete line of acid and blocked acid (latent) catalysts available. While acid catalysts provide the fastest cure and lower curing temperatures, blocked catalysts are typically chosen for systems requiring greater package stability. In addition, troublesome catalyst-pigment interaction is reduced or eliminated. Suggested Starting Levels Acid Catalysts (Table 1) lists acid catalysts and (Table 3) blocked acid catalysts to fulfill your specific needs. (Table 2) represents the various cure profiles of the acid catalyst based upon a 30 minute cure schedule for a typical Resin/HMMM (75/25 ratio) coating.
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| Nacure® and K-Cure® Acid Catalysts | |||||||||
| Product | Acid
Type Volatile |
% Active | Acid # | Lbs/Gal | Gardner Color |
Min.* Cure |
Attributes/Uses | ||
| Nacure 155 |
DNNDSA Isobutanol |
55 | 112-116 | 8.16 | 12 max. | RT | General purpose catalyst. Excellent water, detergent and salt spray resistance. | ||
| Nacure 1051 |
DNNSA 2-Butoxyethanol |
50 | 60-64 | 8.16 | n/a | 125°C | Best water and corrosion resistance. Recommended for high temperature applications on metal. | ||
| Nacure 5076 |
DDBSA Isopropanol |
70 | 130-140 | 8.17 | 4 | RT | Complies with FDA 21 CFR, Sec. 175.300 (b) (3) xiii (a&b). | ||
| Nacure 4054 |
AAP Isobutanol |
50 | 155-165 | 7.49 | 1 | 110°C | Weak acid for high NH/polymeric melamines and phenolic crosslinkers. 4054J for RT cure. | ||
| K-Cure 1040 |
p-TSA Isopropanol |
40 | 130-140 | 8.25 | 1 | RT | Highest gloss. Fastest cure. Excellent weathering and exterior durability. | ||
| K-Cure 1040W |
p-TSA Water |
40 | 130-140 | 9.40 | 2 | RT | As above, non-flammable for WB applications. | ||
| K-Cure 129B |
Mixed
Acids Methanol/n-Butanol |
50 | 200-210 | 8.90 | 1 | RT | Fastest cure. Wood and paper coatings. | ||
| K-Cure 129W |
Mixed
Acids Water |
50 | 200-210 | 9.85 | 1 | RT | Non-flammable, WB ink and wood coatings. | ||
| RT=Room Temperature, *30 minute cure schedule - Resin/Urea (60/40 ratio) | |||||||||
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| Acid Catalysts - Suggested Starting Levels | |||||||||
| Product | 70°C | 90°C | 110°C | 125°C | 150°C | 175°C | 200°C | ||
| N-155 | 4.7% | 2.7% | 1.6% | 1.2% | 0.6% | 0.5% | 0.3% | ||
| N-1051 | NR | NR | NR | 2.2% | 1.4% | 0.9% | 0.6% | ||
| N-5076 | 4.5% | 2.5% | 1.5% | 1.1% | 0.7% | 0.5% | 0.3% | ||
| N-4054** | NR | NR | 4.0% | 2.0% | 1.0% | NR | NR | ||
| K-1040/1040W | 4.2% | 2.3% | 1.4% | 1.0% | 0.7% | 0.4% | 0.3% | ||
| K-129B/129W | 2.6% | 1.5% | 0.9% | 0.7% | 0.4% | 0.3% | 0.2% | ||
| **30 min. cure schedule, catalyst (as supplied) on Total Resin Solids - High NH Polymeric melamine, NR=Not Recommended | |||||||||
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| Nacure® Blocked Catalysts | |||||||||
| Product | Acid
Type Volatile |
% Active | pH | Lbs/Gal | Gardner Color |
Min.* Cure |
Attributes/Uses | ||
| Nacure X49-110 |
DNNDSA Isobutanol/ Isopropanol |
25 | 6.5 - 7.5 | 7.55 | 10 max. | 90°C | Best overall properties. Excellent water and corrosion resistance, adhesion. | ||
| Nacure 3525 |
DNNDSA Isobutanol/ Isopropanol |
25 | 7.0 - 8.5 | 7.65 | 10 max. | 120°C | Better solubility than X49, slower curing. Good salt spray resistance and adhesion. | ||
| Nacure* XP-383 |
DNNDSA Xylene |
25 | n/a | 8.20 | 10 max. | 120°C | Low conductivity for electrostatic spray. High gloss, reduced pigment interaction. | ||
| Nacure 3327 |
DNNDSA Isobutanol/ Isopropanol |
25 | 6.5 - 7.5 | 7.40 | 10 max. | 107°C | Better solubility than other amine blocked DSA catalysts. | ||
| Nacure 1323 |
DNNSA Xylene |
21 | 6.8 - 7.5 | 7.43 | n/a | 150°C | High temperature applications. Excellent solubility in aromatic and aliphatic solvents. | ||
| Nacure* 1419 |
DNNSA Xylene/ MIBK |
30 | n/a | 7.74 | n/a | 150°C | Electrostatic spray. High bake applications for water, detergent and salt spray resistance. | ||
| Nacure 1557 |
DNNSA Butanol/ 2-Butoxyethanol |
25 | 6.5 - 7.5 | 7.56 | n/a | 150°C | Resolves solvent popping in thick films. Excellent humidity and detergent resistance. | ||
| Nacure 5225 |
DDBSA Isopropanol |
25 | 6.0 - 7.0 | 7.40 | 2 | 120°C | Best solubility in high solids enamels. Good solubility in aliphatic solvents. | ||
| Nacure* 5414 |
DDBSA Xylene |
25 | n/a | 8.30 | 4 | 120°C | Polymeric blocked. Excellent electrostatic spray (non-aqueous). Good intercoat adhesion. | ||
| Nacure 5528 |
DDBSA Isopropanol |
25 | 7.0 - 8.0 | 7.50 | 2 | 120°C | Broad solubility. Excellent color stability. | ||
| Nacure 5925 |
DDBSA Isopropanol |
25 | 7.0 - 7.5 | 7.50 | 2 | 130°C | Complies with FDA 21 CFR, Sec. 175.300 (b) (3) xiii (a&b). | ||
| Nacure 2107 |
p-TSA Isopropanol |
25 | 8.0 - 9.0 | 7.57 | 1 | 90°C | Good metal mark resistance. | ||
| Nacure 2500 |
p-TSA Isopropanol |
26 | 6.0 - 7.0 | 8.15 | 1 | 65°C | Low temperature cure. Excellent stability. | ||
| Nacure 2501 |
TSA Methanol/ Isopropanol |
25 | 6.0 - 7.2 | 8.01 | 1 | 80°C | Slightly higher resistivity than 2500. Better ketone solubility. | ||
| Nacure 2530 |
p-TSA Methanol/ Isopropanol |
25 | 5.7 - 6.5 | 7.90 | 1 | 65°C | Low temperature cure. Low tendency to yellow or wrinkle. | ||
| Nacure 2547 |
p-TSA Water |
25 | 8.0 - 9.0 | 9.18 | 1 | 107°C | Readily soluble in waterborne systems. Solvent-free. | ||
| Nacure 2558 |
p-TSA Ethylene Glycol |
25 | 3.5 - 4.5 | 9.64 | 1 | 80°C | Excellent control of popping/blistering. | ||
| Nacure XP-357 |
p-TSA Methanol |
20 | 2.0 - 4.0 | 8.00 | 1 | 65°C | Rapid cure, very low tendency to yellow. | ||
| Nacure XP-386 |
p-TSA Water |
47 | 6.1 - 6.4 | 9.29 | 1 | 80°C | Fast cure for laminating adhesives and WB coatings. | ||
| Nacure XP-2211 |
p-TSA Water |
54 | 7.2 - 8.5 | 9.80 | 1 | 80°C | Rapid cure for thermoset waterbornes. Overprint varnish. | ||
| Nacure 4167 |
Acid
Phosphate Isopropanol/ Isobutanol |
25 | 6.8 - 7.3 | 7.16 | 2 | 80°C | Blocked phosphate for high NH/polymeric melamines. Good stability. | ||
| Nacure XP-297 |
Acid
Phosphate Water/ Isopropanol |
25 | 6.5 - 7.5 | 8.20 | 2 | 90°C | Aqueous systems using high NH/polymeric melamines. | ||
| Nacure XP-4575 |
Acid
Phosphate Methanol/ Butanol |
25 | 7.0 - 8.0 | 8.3 | 2 | 110°C | High gloss. Superb storage stability with polymeric amino resins. | ||
| * Covalently blocked products, n/a=Not Applicable | |||||||||
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